Study on the interface of CVD diamond film on molybdenum sheet
By means of metallographic microscope, SEM, EDAX of molybdenum piece of CVD diamond film on the interfacial morphology and composition were studied, compared with magnetic field and without magnetic field by the deposition of diamond film cross-sectional……
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New ray protection material: high gravity tungsten alloy
As a new type of ray protection material, tungsten heavy alloy has been widely used in various kinds of CT, linear accelerator, PET, γ camera and other medical equipment, it can provide better ray protection and beam guidance.
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Some main uses of molybdenum products
Molybdenum charge products:Stainless steels, alloy steels, tool steels and high speed steels are usually smelted in an electric arc furnace. The initial charge generally contains alloy steel scrap, pig iron and some form of molybdenum to obtain the appropriate composition.
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What is the difference between ferro-nickel and ferro-molybdenum
Nickel iron:The main components of nickel-iron are nickel and iron, and also contain Cr, Si, S, P, C and other impurity elements. Nickel is a yellowish silvery white metal, is a magnetic transition metal.
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Characteristics and application of medical tungsten alloy shielding parts
1. Radiation therapy:The use of one or more ionizing radiation for the treatment of malignant tumors.
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High temperature performance of molybdenum lanthanum and TZM alloys
Refractory molybdenum has excellent high temperature strength, creep resistance and low thermal expansion coefficient, Good thermal conductivity and corrosion resistance, so it is used in the electrical industry, aerospace industry and energy industry.
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The role of molybdenum
Tool steel and high-speed steel:One of the earliest applications of tantalum was used as a substitute for tungsten in tool steel and high-speed steel, which was effective and inexpensive.
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The application of the molybdenum
Oil industry pipes:The continuous exploration of new sources of oil has made the development and development of deep oil layers necessary, and deep oil layers are often contaminated with corrosive hydrogen dioxide, carbon dioxide and perchlorinated brine, so that the AISI4100 series Cr-Mo steels containing 0.15% to 0.25% molybdenum are widely used.
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The purpose of the molybdenum
Black material:Alloy steel, stainless steel, tool steel and cast iron are the main application areas of palladium, and their production volume determines the demand for palladium, whose role in the above-mentioned steel is as follows:
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Molybdenum chemical products
Molybdenum, chromium and aluminum salts can be deposited together to form molybdenum chromium red pigment. Molybdate ion and iron ion on the metal surface form insoluble Fe2 (MoO4) 3, which passivates the metal surface and achieves the effect of rust prevention.
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Aviation and nuclear industry
Due to its excellent heat resistance and high temperature mechanical properties, molybdenum alloy can be used as flame guide and combustion chamber of aircraft engine, throat, nozzle and valve of liquid rocket engine of aerospace vehicle, end of reentry vehicle, skin, wing and guide plate of satellite and spaceship, and protective coating material.
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Environmental protection
It is more and more clearly recognized that molybdenum plays an important role in controlling environmental pollution. The large-scale application of molybdenum containing stainless steel greatly reduces the impact on the environment caused by corrosion.
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Oil exploitation
In the development of sour natural gas and oil fields in low-lying areas and the development of subsea oil and gas fields, not only a large amount of H2S gas is produced, but also the seawater erosion makes the drilling pipeline sulfurized brittle and corroded rapidly.
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Molybdenum silicide
(MoSi2) is a widely used electric heating element material, which has the characteristics of high temperature oxidation resistance, excellent corrosion resistance and high melting point.
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High temperature components
Due to its high purity, high temperature resistance and low vapor pressure, molybdenum is often used to make heater and structural material of high temperature furnace. In the production process of tungsten, molybdenum and cemented carbide, the reduction furnace and sintering furnace are mostly made by molybdenum wire heating.
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Automobile spraying
The melting point of molybdenum is as high as 2620 ℃, and it has good high temperature performance and corrosion resistance. Molybdenum has strong adhesion with steel, so it is the main thermal spraying material in the production of automobile parts.
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Agricultural Fertilizers
Molybdenum is one of the essential "trace elements" in plants, accounting for about 0.5ppm of plant dry matter, which is indispensable and irreplaceable. In recent years, ammonium molybdate has been widely used as trace element fertilizer at home and abroad……
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Electronic and electrical
Molybdenum has good conductivity and high temperature performance, especially close to the thermal expansion coefficient of glass. It is widely used in manufacturing the core wire, lead wire, hook, bracket, side bar and other parts of spiral filament in bulb, and as grid and anode support material in electron tube.
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Steel industry
According to the world molybdenum consumption statistics, the application of molybdenum in iron and steel industry still occupies the most important position. As an alloying element of steel, molybdenum can improve the strength of steel, especially the high temperature strength and toughness;
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In recent years, the exploitation, smelting and processing of molybdenum in China have developed rapidly
According to information, in 2001, China produced 72000 tons of molybdenum concentrate, 33000 tons of molybdenum oxide, 7600 tons of ferromolybdenum, 9500 tons of various ammonium molybdate, 1183 tons of molybdenum bars……
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Molybdenum
Molybdenum reserves on the earth are relatively small, accounting for only 0.001% of the weight of the earth's crust. The total molybdenum reserves are about 15 million tons, mainly distributed in the United States, China, Chile, Russia, Canada and other countries.
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High purity tungsten target developed by Institute of aerospace materials and technology can replace imported tungsten target
At present, more and more chips in our country are gradually localized, but many domestic chip production lines are imported, and the target material, as the key component of the chip production line, basically depends on import.
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The high purity tungsten target material for chip manufacturing has been made in China
In semiconductor integrated circuits, thin film science is a very important research field in developing and manufacturing semiconductor devices. The target material is the key material in the surface coating technology.
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The difference of molybdenum target, rhodium target and tungsten target
Molybdenum target refers to that the anode of X-ray tube is made of molybdenum (MO). The relative energy of molybdenum target ray is relatively low, which is "soft" ray. Under the condition of lower tube voltage required by mammography, it is especially suitable for mammary glands with more adipose tissue and lower density of parenchyma, or with smaller thickness and higher density of parenchyma.
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Classification of tungsten electrodes
Cerium tungsten electrode
Cerium oxide is added to tungsten to produce cerium tungsten electrode.
Cerium tungsten has the following advantages over thorium tungsten
*Non radiation * low melting rate * long welding life * good arcing performance. Therefore, Ce-W is the best substitute for Th-W in low current welding environment.Ce-W electrode is mainly used in low current DC welding.
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Tungsten electrode
Because of the characteristics of tungsten, it is very suitable for TIG welding and other electrode materials similar to this kind of work. Adding rare earth oxide to tungsten metal to stimulate its electron work, the welding performance of tungsten electrode can be improved:
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Tungsten heavy alloy shield
The shielding parts of high specific gravity tungsten alloy are made of "high density alloy", which is based on tungsten and added with a small amount of Ni, Co, Mo and other elements.
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Application of molybdenum and its alloys
With the development of science and technology, the application of molybdenum in high technology and other fields is also increasing. Next, let's learn about the application of molybdenum and its alloys.
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Can a giant tungsten ball with a diameter of 100 meters be thrown into the crater and directly hit the center of the earth?
Someone asked: if you throw a huge tungsten ball with a diameter of 100 meters into a crater, can the tungsten ball sink to the center of the earth?
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The melting point of tungsten is higher than that of rhenium. Why is rhenium alloy more suitable for Aeroengine Blades?
Although the melting point of tungsten is higher than that of rhenium, the processing difficulty of tungsten alloy is also higher, which is more brittle at high temperature and easier to be oxidized;
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Classification of molybdenum and molybdenum materials
1. Pure molybdenum and high purity molybdenum
(1) Pure molybdenum
It includes sintered molybdenum products (such as crucible, etc.) and processing molybdenum plate, molybdenum bar, molybdenum strip, molybdenum wire, molybdenum sheet and profile, etc.
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Application of molybdenum and its alloys
Improving the properties of molybdenum and molybdenum alloy is an inevitable way to expand the application field and meet the increasing performance requirements. A series of researches on high performance molybdenum and molybdenum alloys have been carried out at home and abroad.
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Application of molybdenum and its alloys
With the development of science and technology, the application of molybdenum in high-tech and other fields is also increasing. Let's take a look at the application of molybdenum and its alloys.
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Preparation and processing of molybdenum and molybdenum alloy products
At present, the main manufacturing methods of molybdenum and molybdenum alloy products are smelting, powder metallurgy, chemical vapor deposition, rolling and forging.
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Application of molybdenum and molybdenum alloy products
In refractory metals, molybdenum and its alloys have good thermal conductivity, conductivity and low expansion coefficient. They have high strength at high temperature (1100 ~ 1650 ℃), and are easy to process compared with tungsten. Therefore, their products are widely used in aerospace and nuclear industries, electronics, building materials, instruments and other industries.
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Application of molybdenum in electronic industry
Molybdenum was used in the early electronic industry. With the emergence of solid-state electronics, a new application field is gradually formed; the current application depends on the metal's high melting point, high heat transfer, machinability, strength and sinter ability.
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Cold rolling of wide width molybdenum plate
Molybdenum plate with width from 400mm to 510mm is carried out on 550mm cold rolling mill, while molybdenum plate with width from 700 mm to 800mm is carried out on 1200mm four high reversing cold rolling mill.
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What are the high temperature properties of Mo La and TZM alloys?
The high temperature properties and microstructure of Mo La alloy and TZM alloy at 1000 ~ 1800 ℃ were studied. The results show that the molybdenum lanthanum alloy has higher comprehensive properties of strength and plasticity when the temperature is less than 1400 ℃.
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Production method of molybdenum and molybdenum alloy materials
Molybdenum and molybdenum alloy materials can be made by stamping, metal processing and welding. The surface of molybdenum alloy is processed with high precision. However, attention should be paid to the fact that molybdenum has high temperature strength but poor room temperature strength, and its toughness is not as good as that of carbon steel or brass.
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Tungsten alloy die casting
Die castings can be processed with nonferrous metals and alloy iron, made from large amounts of molybdenum or tungsten, or with a small amount of zirconia. Die castings are usually used for multi face pressing and are specially designed to prevent delamination or cracking when pressing the bar.
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Cause analysis of small black spots on molybdenum disc
After high temperature sintering, molybdenum powder is rolled into molybdenum discs. After polishing and corrosion, it is found that some batches of molybdenum discs have defects such as edge falling, delamination and small black spots on the surface.
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Discussion on vacuum sintering technology of molybdenum bar
Since the great development of vacuum sintering technology in cemented carbide production practice in 1960s, vacuum sintering technology has also been applied in the field of tungsten molybdenum powder metallurgy.
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Separation of tungsten and molybdenum
The molybdenum content of tungsten products is very strict, because the existence of molybdenum will seriously affect its performance. Limit its application scope. The chemical properties of tungsten and molybdenum are very similar, so it is very difficult to separate tungsten from molybdenum.
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Production method of super large tungsten crucible
Since the service temperature of high temperature vessel of single crystal furnace is over 2000 ℃, tungsten crucible is the only choice for high temperature vessel of single crystal furnace.
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Straightening device for molybdenum strip processing
As a derivative of raw material molybdenum wire, molybdenum strip is widely used in lighting industry, mainly used in high-pressure mercury lamp, high-pressure sodium lamp, metal halide lamp, film and television light source, and its quality has a great impact on the lamp life and interface welding quality.
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Discussion on combined die for pressing molybdenum crucible
Molybdenum is a kind of high temperature resistant material. It is widely used in modern industry, but its price is high. In order to reduce the cost, powder metallurgy production method is widely used to manufacture molybdenum products. Molybdenum crucible is one of them.
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Standardization of molybdenum wire
Molybdenum wire has high melting point, high strength and elastic modulus, small expansion coefficient, low vapor pressure, good electrical and thermal conductivity and excellent corrosion resistance.
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Effect of hot isostatic pressing on near net forming of tungsten shaped parts by plasma spraying
Tungsten has excellent properties such as high melting point, high density and good high temperature conductivity. It plays an important role in national defense industry and national economy, especially in aerospace, nuclear industry and other cutting-edge fields.
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Study on texture of cold rolled pure molybdenum sheet
When the metal material is deformed, the crystal will rotate, and most of the crystals will gather in some orientation position (or deviate from the random distribution), which is the result of texture formation.
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Measures to reduce fracture probability and increase yield of molybdenum wire
In order to improve the yield of molybdenum wire and reduce wire breakage, the quality of raw materials should be improved firstly, and then the drawing process should be standardized and stabilized:
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Application of tungsten and molybdenum in high temperature furnace construction materials
Due to the metal, ceramics, such as composite materials, the requirements of modern manufacturing technology for its heat treatment has become higher and higher, so the relevant production conditions have become increasingly stringent.
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Manufacture of tungsten and molybdenum and addition of alloying elements
The preparation of tungsten, molybdenum products is mainly realized by powder metallurgy. After the ore is refined and then reduced (the oxides of W and Mo are reduced in hydrogen) to obtain the corresponding metal powder (purity above 99.9%).
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Tungsten pellets reinforced Bulk Amorphous Composites
Under uniaxial tension and compression, the single-phase amorphous alloy has high strength (about 2 GPa) and elastic strain (about 2%). However, the failure of amorphous alloy along a single shear band shows the characteristics of brittle material, that is, there is almost no plastic deformation.
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Research on spinning temperature control of thin walled tungsten tube
Tungsten has unique characteristics, which is an important material for high temperature heating body and high temperature heat insulation. Its brittleness brings great difficulties to its deep processing, especially in the spinning thinning process of P / M tungsten tube blank under multi-directional force, even if the tube blank with good deformation performance can be produced.
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Porous tungsten with controllable porosity by low temperature sintering
Porous tungsten as a high current density cathode is one of the important applications of tungsten. Its porous framework is an important part of reserve cathode. The framework should be impregnated with electron emission compounds.
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Recovery of tungsten and vanadium from waste tungsten metal products
Tungsten, due to its unique physical and chemical properties, is widely used in the field of high temperature resistance and high strength. However, the content of tungsten in the earth's crust is very low, and the resources are also continuously depleted.
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Separation of molybdenum disc and monocrystalline silicon from failed silicon molybdenum components by chemical method
Molybdenum disc is the support of contact electrode and silicon rectifier of silicon controlled silicon element. With the rapid development of electronic industry, the output of silicon molybdenum components is also increasing.
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Factors affecting porosity of porous tungsten
Porous tungsten and its components based on porous tungsten are widely used in aerospace, power electronics and metallurgical industry. For example: vaporizer of mercury ion rocket engine;
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Analysis on spinning process of molybdenum crucible
Roller track:The roller track of molybdenum crucible is in the order of a → B → C → D → e → f → g → h → I → J → K. It is composed of five curves, namely, the forward cutter curve, the reverse cutter curve, the feed curve, the die sticking curve and the exit curve.
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Characterization of porous tungsten materials
Pore characteristics:The basic physical phenomenon of mercury intrusion method is to force non wetting and non reactive liquid mercury into porous samples under a given external pressure.
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Spinning technology of molybdenum crucible
Molybdenum is a rare metal, an important non renewable strategic material, and an important basic material for realizing national modernization and building modern national defense. Molybdenum is a non renewable resource. With its increasingly extensive application, the demand is increasing, and its price is getting higher and higher.
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Cryogenic processing of porous tungsten framework
The porous tungsten framework sintered at high temperature is easy to be brittle and cannot be machined. As mentioned above, tungsten copper (plastic) material is obtained by infiltrating copper or plastic to improve its processing performance, and then turning is carried out.
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Copper infiltration of porous tungsten framework
The porous tungsten billets sintered at high temperature are brittle and can not be machined. The turning performance can be improved after copper infiltration.
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Review of porous tungsten matrix materials for diffusion cathodes
In microwave vacuum electronic devices, cathode as an electron emission source, its performance directly affects the performance and life of the device, which is referred to as the "heart" of vacuum electronic devices.
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Microstructure and crystal orientation of pure tungsten formed by selective electron beam melting
As an important refractory metal material, tungsten has the characteristics of high melting point, high thermal shock resistance, high thermal conductivity, low expansion coefficient, low vapor pressure and good radiation resistance. It has extremely important applications in aerospace, nuclear industry, chemical industry and other extreme environment fields.
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Mechanical properties of pure molybdenum in micro and nano scale during high pressure torsion
Because of its high strength at room temperature and high temperature, excellent wear resistance, corrosion resistance and good thermal physical properties, refractory metal molybdenum is widely used in aerospace, electrical and electronic fields.
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Preparation of high purity molybdenum target
(1) Molybdenum alloy with purity over 99.9% produced by sputtering method is used as raw material. Molybdenum alloy is put into the feeding device of electron beam cooling bed furnace, that is, spiral tube.
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The production process of blade molybdenum foil belt
Molybdenum foil has pure molybdenum foil and rare earth molybdenum foil. The addition of rare earth oxides to molybdenum can significantly improve the microstructure, recrystallization temperature and high temperature properties of the materials. Due to the different physical and chemical properties of different rare earth oxides, the properties of alloy materials are different.
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Hot working method of molybdenum rhenium alloy ingot by electron beam suspension melting
Because of its good room temperature plasticity, high temperature strength and good plasticity after recrystallization, molybdenum alloys are widely used in electric vacuum devices, such as grid insulation screen.
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Introduction to separation and enrichment of molybdenum and rhenium
Ion exchange separation of molybdenum and rhenium is based on the high selectivity of the resin for specific ions such as mo. baht. In the solution, Lai and Mo exist in the anion form of REO * and moo.
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The important role of tungsten based alloy in national defense and national economic construction
(1) Application in aerospace industry. The first generation of tungsten based high specific gravity alloys developed in China in the 1960s were developed. Since its birth, it has been successfully used in the navigator of the first man-made satellite developed by China.
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Production of molybdenum disc
Because of its high strength, good thermal conductivity and good processing performance, molybdenum is used as the substrate material of silicon rectifying elements and silicon controlled silicon components (the support of silicon wafer molybdenum disc).
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A simple and rapid grinding method for tungsten rod
Among many welding methods, TIG and plasma arc welding are developing rapidly. In pressure vessel, boiler and chemical equipment manufacturing industry, the former is widely used in the welding of thin-walled pipe, thick wall pipe and nozzle back weld, stainless steel pipe fittings and forming parts, and the latter is used in aerospace, nuclear energy, electronics, shipbuilding and other industrial sectors.
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Quality control of molybdenum wafer production
Quality of raw materials: the quality of raw materials directly affects the product quality of molybdenum wafers, and directly affects the parameters of silicon rectifying elements and silicon controlled silicon elements.
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Application of molybdenum
Molybdenum is a refractory metal. Molybdenum and its alloys have been widely used in aerospace, national defense, military industry, electronic and electrical metallurgy and glass industry because of their excellent electrical conductivity, thermal conductivity, corrosion resistance, low thermal expansion coefficient, high hardness and high temperature strength.
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The role of molybdenum alloy elements
Molybdenum is usually strengthened by microalloying, carbide strengthening, solution strengthening and dispersion strengthening. (1) Micro alloying is mainly to add trace Ti, Zr, B, La and other alloy elements, the amount of which is 0.1% ~ 1% for solution strengthening.
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Study on high temperature oxidation resistance of molybdenum and its alloys
Molybdenum is a refractory metal. Key and its alloys are widely used in aerospace, defense and military industry, electronic and electrical, metallurgy and glass industry due to their excellent electrical conductivity, thermal conductivity, corrosion resistance, low thermal expansion coefficient, high hardness and high temperature strength.
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Production method of molybdenum and molybdenum alloy materials
Molybdenum and molybdenum alloy materials can be made by machining, forming, metal processing and welding. The surface of molybdenum and molybdenum alloy is smooth and high precision after machining.
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Application of molybdenum and molybdenum alloy
Electronic power equipment manufacturing industry is the main application field of molybdenum and molybdenum alloy materials. It includes filament, lighting and electronic tube components, special printed circuit board coating, microwave devices, medical electronic and electrical equipment, internal components of light tube ……
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Research status and development trend of molybdenum and molybdenum alloy sputtering targets
Molybdenum belongs to refractory metal, body centered cubic structure, with good conductivity and thermal conductivity, low thermal expansion coefficient, good corrosion resistance and environmental friendly and other sub components and electronic products, such as thin film semiconductor tube liquid crystal display (TFT-LCD) plasma display, field emission display, touch screen, can also be used in solar cell back electrode, glass coating and other fields.
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Preparation and sputtering properties of pure molybdenum target for TFT-LCD
In modern TFT-LCD manufacturing, molybdenum film is mainly used as the barrier layer of Al in conductive film, and part of molybdenum film is used as barrier layer of Al in conductive film.
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Tungsten target
Tungsten targets are mainly used in aerospace, rare earth smelting, electric light source, chemical equipment, medical equipment, metallurgical machinery, smelting equipment, petroleum, etc.
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Application analysis of tungsten alloy machining
Tungsten alloys have many excellent properties after high temperature liquid phase sintering, such as high density, high melting point, high hardness, wear resistance, high tensile strength, high elongation, high temperature resistance, etc.
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Effect of molybdenum foil width on small mass spectrometer experiment
The influence of molybdenum foil width on the experiment was analyzed by analyzing the structure, working principle, sensitivity and measuring range of the magnetic deflection mass spectrometer. The optimum width of molybdenum strip is 0.60-1.00mm.
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Effect of rolling mode on molybdenum plate
During unidirectional rolling, banded cell structure is formed in the molybdenum plate, which results in obvious anisotropy. The cross rolling is to process the molybdenum plate in the longitudinal and transverse directions, which can strengthen the uniformity and equiaxed effect of the internal structure of the material, effectively reduce the anisotropy of the material and improve its deep drawing performance;
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Blooming and rolling of molybdenum sheet
The quality of the slab with open edge at 1 300 ℃ and 1 400 ℃ is good. If the opening temperature is too high, it will not only make the grains coarse and waste resources, but also have a negative impact on the structure and properties of the finished molybdenum sheet……
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Key to production of high quality molybdenum plate
With the unprecedented development of the national economy, molybdenum and its alloys have been applied to the fields of electronics, machinery, aviation, military and so on in various forms.
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Effect of annealing process on hot formability of molybdenum lanthanum alloy thick plate
Due to its high melting point, excellent high temperature strength, good conductivity and thermal conductivity, high wear resistance, good processability and low cost, molybdenum has become an ideal high temperature structural material under harsh conditions.
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Application of molybdenum sheet
In the application of molybdenum products, sheet is the most widely used. When it is used to make all kinds of electric vacuum devices, molybdenum sheet should not only have enough strength, but also high plasticity and low anisotropy.
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Mechanical properties of molybdenum plate
The tensile strength, yield strength and elongation of 0.5mm thick molybdenum plate annealed by different processes were measured by shear tensile test on electronic universal tensile testing machine (see table).
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The appearance of molybdenum is not amazing, and the use is wide
Although molybdenum has been discovered for more than 200 years, its large-scale development and utilization is still in this century, especially in recent decades.
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Show molybdenum’s talents
The outbreak of the first World War led to a sharp increase in the demand for tungsten, and the supply of ferrotungsten was extremely tight. Therefore, molybdenum replaces tungsten in many high hardness and impact steels.
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Molybdenum, a mysterious "strategic" metal, is not surprising in appearance, but is widely used!
Molybdenum is a transition metal element with a value of 42 on the periodic table. Its chemical symbol is molybdenum. Molybdenum is silvery white, hard and tough. It does not react with hydrochloric acid or hydrofluoric acid.
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Gnaw down the hard bone of scientific research! From a big tungsten resource country to a powerful tungsten manufacturing country, they have been persisting for decades
There were 18 technicians who did not rest that summer in 1991. They translated the basic documents of foreign equipment, such as reduction furnace and airflow disperser, in the field of tungsten and gold manufacturing word by word.
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The operation of tungsten and molybdenum industry has basically recovered and improved
The monitoring results of monthly prosperity index of China's tungsten and molybdenum industry show that in July, the prosperity index of China's tungsten and molybdenum industry was 25.1, up 2.6 points from the previous month, and has entered the "normal" range; the first composite index was 44.5, up 0.1 point compared with the previous month.
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Properties of molybdenum
The properties of molybdenum and tungsten are very similar, its boiling point and conductivity are outstanding, and its linear thermal expansion coefficient is small, so it is easier to process than tungsten.
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Requirements of high quality molybdenum slab and Study on its processing technology
Molybdenum is a rare metal with high melting point (2620 ± 10 ℃), high elastic modulus (320-360 GPA), small linear expansion coefficient (20-100 ℃, 5.8x10-6-6.2x10-6), high melting point, low steam pressure and low evaporation rate.
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Molybdenum target of the sixth generation AMOLED panel
The reason why liquid crystal displays such as mobile phones and televisions can display images depends on a thin layer of metal film on the glass substrate that can not be seen by the naked eye.
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Application, preparation and development of molybdenum sputtering targets
Sputtering, as an advanced thin film preparation technology, has two characteristics: high speed "and" low temperature ". It uses the ions produced by the ion source to accelerate the aggregation of high-speed ion current in vacuum and bombard the solid surface.
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Application of molybdenum
Molybdenum is widely used in the downstream, and is currently used in iron and steel industry, machinery, electronics, mining, agriculture, medicine and other fields, is an important resource.
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Spherical agglomerates of molybdenum powder
Super heat resistant alloy and nickel base alloy molybdenum can improve the corrosion resistance of stainless steel, and it can also enhance the corrosion resistance and mechanical properties of nickel base alloy. Many nickel base alloys with high molybdenum content and strong corrosion resistance are widely used in many fields.
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Molybdenum resources
Storage molybdenum never appears as a natural element, but is always combined with other elements. Although many molybdenum minerals have been discovered, molybdenite (MoS2), a natural sulfide of molybdenum, is the only one with industrial mining value.
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Properties and main uses of molybdenum
The properties of molybdenum and tungsten are very similar. Its boiling point (5560 °) and electrical conductivity are outstanding, and the coefficient of linear thermal expansion is small. The results show that the thermal conductivity [135 w / (m · K)] and specific heat [0.276 KJ / (kg · K)] are the best combination, which makes it a natural choice for thermal shock resistance and thermal fatigue resistance.
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Characteristics of tungsten and molybdenum
Tungsten and molybdenum materials are often used in different industries because of the following nine properties:
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Molybdenum powder
Molybdenum and molybdenum alloys have the characteristics of high temperature strength and high temperature hardness, good thermal and electrical conductivity, and good corrosion resistance. Therefore, it is widely used in chemical industry, metallurgy and aerospace industry.
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Application of molybdenum and molybdenum alloy
The high melting point of molybdenum has become one of the main technical problems in the production of molybdenum. However, for the rapidly developing industry in the 20th century, it is the high melting point that attracts people. Almost every technological leap has something to do with the application of molybdenum.
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Main uses of tungsten
Tungsten and its alloys are widely used in electronic and electric light source industries. It is used to manufacture all kinds of light bulbs. The filament of electron tube is made of doped tungsten filament with anti droop property.
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Properties of tungsten
The melting point of tungsten is 3410 ℃, the boiling point is about 5900 ℃, and the thermal conductivity is 174 w / m · K at 10-100 ℃. At high temperature, the evaporation rate is slow and the coefficient of thermal expansion is very small.
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The chemical properties of tungsten and molybdenum and the reaction with gases
Tungsten and molybdenum react with carbon and carbonaceous gases: all kinds of carbonaceous gases and solid carbon (carbon black, coal, graphite) react with tungsten and molybdenum in the range of 1000-1200 ℃, forming carbides (W3C, WC and Mo2C, MOC), and the reaction is intensified at 1400-1600 ℃. Even if there is a small amount of carbide impurity in tungsten and molybdenum, it will make tungsten and molybdenum brittle.
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Tungsten disulfide nanosheets are expected to improve the performance of LiFePO4 cathode materials
Tungsten disulfide nanosheets are expected to improve the performance of LiFePO4 cathode materials. In the industrialization of lithium-ion battery, cathode materials are becoming the main bottleneck of its development.
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How to break through 3 nanometers down? Selective tungsten process to solve the major bottleneck of planar micro reduction
His is the first layer of circuit that links transistors with other circuits in the chip. With this innovative selective deposition technology, the contact resistance that affects transistor performance and increases power consumption can be reduced.
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Application of molybdenum needle in racing car
Molybdenum pin, also known as molybdenum needle. It is like a needle like molybdenum product, its surface is bright and smooth. Due to its high melting point, corrosion resistance, good tensile strength and low coefficient of thermal expansion, molybdenum needle is widely used in electronic, chemical, mechanical equipment, electroplating equipment, environmental protection equipment and precision processing industries.
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Advantages of molybdenum electrode
The main component of molybdenum electrode is molybdenum, which is prepared by powder metallurgy process. The content of molybdenum electrode is 99.95% and the density is more than 10.15g/cm3 to ensure the quality of glass and service life of electrode.
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Advantages of molybdenum electrode
The main component of molybdenum electrode is molybdenum, which is prepared by powder metallurgy process. The content of molybdenum electrode is 99.95% and the density is more than 10.15g/cm3 to ensure the quality of glass and service life of electrode.
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Molybdenum rhenium alloy
Molybdenum rhenium alloy is a kind of alloy composed of molybdenum and rhenium. The alloy shows rhenium effect to improve plasticity. The rhenium content in the alloy is generally 11% ~ 50% (mass fraction).
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Tungsten electrode
At present, ceriated tungsten electrode, which has no radioactive pollution, is a green environmental protection product. It can start arc easily with a small current, and the arc current is relatively small. Under the condition of low current direct current, ceriated tungsten electrode is very popular.
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Why is pure tungsten rarely used in TIG welding?
Argon arc welding (TIG) of tungsten plate is gas shielded welding with tungsten needle as one electrode of arc. Tungsten electrode, as an immiscible electrode, requires high melting point, less volatilization at high temperature and high strength at high temperature! The melting point of tungsten is 3690k, its boiling point is 5900k, and its red heat intensity is high. It is an ideal non melting electrode material.
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Tungsten Rhenium Alloy
The alloy based on tungsten with rhenium is a kind of tungsten alloy. The typical rhenium contents in the alloy are 1%, 3%, 5%, 10%, 20%, 25% and 26%, etc. Microcracks are often formed on the interface of tungsten.
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Platinum tungsten alloy
The platinum alloy is composed of platinum base and tungsten. It forms a simple peritectic phase diagram, and the peritectic reaction temperature is about 2460 ℃. With the increase of tungsten content, the strength of Pt-W alloy increases significantly.
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Niobium Tantalum Tungsten alloy
A niobium alloy is formed by adding a certain amount of tantalum and tungsten based on niobium. This kind of alloy has high tensile strength at high temperature and creep deformation resistance, so it has important application in spacecraft.
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Tantalum Tungsten alloy
Tantalum based alloy is formed by adding a certain amount of tantalum. The Ta-W binary alloy composed of TA and W is an infinite solid solution. The strength of the alloy increases with the increase of tungsten content, but the plasticity of recrystallized alloy decreases significantly when the content of tungsten exceeds 12% ~ 14%.
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Silver Tungsten Alloy
A silver alloy consisting of silver and tungsten. Silver and tungsten are immiscible in both liquid and solid state. Silver tungsten alloy can only be made into sintered materials by powder metallurgy or extrusion.
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High density tungsten alloy
A tungsten alloy based on tungsten and added with nickel, iron, copper, and other elements. The tungsten content of the alloy is 85% ~ 98%, which is prepared by powder metallurgy process. The alloy was first invented by J.C. McLennan in 1935.
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Molybdenum tungsten alloy
It includes molybdenum tungsten alloy based on molybdenum and tungsten molybdenum alloy series based on tungsten. The alloy can be formed in any proportion and is a complete solid solution alloy at all temperatures.
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Tungsten inert gas welding
Under the protection of inert gas, an arc welding method is used to melt the base metal and filler metal (if filler metal is used) by using the arc generated between the tungsten electrode and the workpiece, referred to as TIG welding.
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Tungsten
In addition to carbide, tungsten partly dissolves into iron to form solid solution. Its effect is similar to that of molybdenum, and its general effect is not as significant as that of molybdenum. The main pattern of tungsten in steel is to increase tempering stability, red hardness, thermal strength and wear resistance due to carbide formation.
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Molybdenum
Molybdenum in steel can improve hardenability and thermal strength, prevent temper brittleness, increase remanence and coercivity and corrosion resistance in some media.
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Molybdenum copper alloy cast iron
Molybdenum Copper alloy cast iron is the material of roll, and roll is a large consumption accessory in steel rolling production. The quantity and quality of rolled steel are closely related to roll. Automation, continuous and heavy rolling process are the development direction of modern rolling technology.
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Tungsten copper integral contact, rivet type integral tungsten copper contact
The manufacturing method of rivet type tungsten copper and silver tungsten all contacts is to make tungsten copper and copper materials at one time, and then the material is formed by mechanical manufacturing. Advantages and features l the bonding part of tungsten copper material and copper material does not use any flux and solder to ensure that the touch resistance of rivet type electrical contact is minimized.
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Molybdenum copper alloy
MoCu alloy is actually a pseudo alloy composed of two immiscible metals, but it has the characteristics of Mo and Cu and has good comprehensive properties. The main characteristics of Mo Cu alloy are as follows:
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How to extract silver from silver-tungsten alloy
To silver tungsten alloys in dilute nitric acid, energetic response due to the silver can dissolve in dilute nitric acid generated, but tungsten can't dissolve in dilute nitric acid, this filter can get rid of tungsten……
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Matters needing attention in tungsten copper electroplating
W-Cu alloy is a two-phase "pseudo alloy" composed of tungsten and copper. Because tungsten is insoluble with other metals, it is difficult to electroplate W-Cu alloy. Tungsten copper alloy electroplating claims are as follows:
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Report on tungsten market operation: 51.28% of the industry's loss in the first quarter
1、 Price of tungsten concentrate drops to cost line operation
From January to may, the price of domestic tungsten concentrate operated in the range of 7400-93000 yuan / ton. After the global spread of the new crown epidemic in mid March, due to market panic, the demand decreased sharply, the price of tungsten concentrate fell rapidly from 93000 yuan / ton, fell to 74000 yuan / ton in mid April, and consolidated at a low level.
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Forging of tungsten, molybdenum and their alloys
1. Forging characteristics of tungsten, molybdenum and their alloys
The melting point of tungsten, molybdenum and their alloys is much higher than that of titanium, and the required forging temperature is very high, all above 1300 ℃. Even at such a high temperature, the deformation resistance is still very high. Therefore, the forging equipment is required to have large capacity and high strength, and the working temperature of the heating equipment is required to be high.
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Tungsten alloy has better function
In the development of filament materials, rhenium or cobalt can further improve the properties of W-Al alloy. When 3% Re is added, the elongation of WAl2 filament annealed at 2750 ℃ for 3 minutes can reach 25.7%. Even when the RE content is as low as 0.25%, the elongation can reach 6%;
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Tungsten smelting process
Decomposition method of tungsten concentrate: fire method and wet method.
① sodium carbonate sintering is commonly used for pyrolysis. In this method, wolframite concentrate and sodium carbonate are placed together in a rotary kiln and sintered at 800-900 ℃.
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Molybdenum: a trace element closely related to life
Molybdenum, like other elements such as copper, iron and zinc, is a trace element closely related to life. Molybdenum exists in human body, animals and plants. So, do you know the relationship between molybdenum and human health, molybdenum and animal health, molybdenum and plant health?
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Key points and classification of TIG welding
TIG welding (abbreviated as tungsten insert gas welding) has been widely used since Hobart and Devers invented the tungsten inert gas welding in 1920s. As the name suggests, TIG welding is a welding method that uses the arc heat generated between the tungsten electrode and the weldment to melt the weldment and filler wire under the protection of inert gas. Its characteristics are as follows:
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Key points and classification of TIG welding
TIG welding (abbreviated as tungsten insert gas welding) has been widely used since Hobart and Devers invented the tungsten inert gas welding in 1920s. As the name suggests, TIG welding is a welding method that uses the arc heat generated between the tungsten electrode and the weldment to melt the weldment and filler wire under the protection of inert gas. Its characteristics are as follows:
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Heat treatment of tungsten and its alloy
Tungsten and its alloy have high hardness and high work hardening speed, so heat treatment must be carried out. For example, for 0.3x200mm thin tungsten plate, the stress shall be eliminated immediately after warm processing, otherwise it may crack by itself, and the cracking is more serious if the processing amount between two annealing is too large (such as 80-90%).
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The earliest application of micro fertilizer in China's Agriculture: Mo fertilizer the earliest application of micro fertilizer in China's Agriculture: Mo fertilizer
When it comes to molybdenum fertilizer, we always start with such a story. This is a strange thing happened in New Zealand pastures several decades ago (at that time): due to the bad weather, the pastures planted by farmers in the pastures are almost short and small, and even yellow and withered. It looks like a yellow ocean in the past. But there is a small plot of grass that grows well, like a small green island. What's the matter?
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Beneficiation and smelting process of tungsten
In the periodic table, tungsten and molybdenum have silver gray luster on the surface of VIB group elements, and the powder is dark gray. Their commonness it is characterized by high melting point, strength and modulus of elasticity, small expansion coefficient, low vapor pressure, good conductivity and thermal conductivity, and superior corrosion resistance. Its disadvantages are low temperature embrittlement and high temperature oxidation.
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Tungsten, molybdenum and their alloys
In the periodic table, tungsten and molybdenum have silver gray luster on the surface of VIB group elements, and the powder is dark gray. Their commonness it is characterized by high melting point, strength and modulus of elasticity, small expansion coefficient, low vapor pressure, good conductivity and thermal conductivity, and superior corrosion resistance. Its disadvantages are low temperature embrittlement and high temperature oxidation.
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Why don't domestic Aeroengine Blades use tungsten with high temperature resistance? Instead, rhenium without rare performance is used
First of all, it should be understood that the working environment of turbine blade in aeroengine is high temperature (above 1000 ℃), high pressure (above 100MPa), and strong centrifugal force. In addition, the blade should work stably in this environment, and it should not creep or damage. This requires high temperature resistance and creep resistance of the materials used for blades.
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Export growth of tungsten products slowed down but the structure improved
Influenced by the trade friction between China and the United States, China's export of tungsten products is limited to some extent, while the real consumption demand for tungsten products in the international market is also gradually weakened.
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Industrial upgrading and gradual improvement of export structure
The technical difficulty of tungsten industry mainly lies in the deep processing. China's cemented carbide is gradually upgrading to high-precision and high-grade products.From the perspective of industrial chain, tungsten ore is processed by coarse crushing, gravity beneficiation and concentration to obtain tungsten concentrate; then ammonium Paratungstate Crystal with high purity and complete crystal varieties can be obtained through alkali pressure boiling, ion exchange, evaporation crystallization and other technologies;
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Production reduction and price protection: tough tungsten price meets strong support
The dominant production of tungsten resources in China is mainly concentrated in South China.China's tungsten resource reserves are 1.9 million tons, accounting for 57.58% of the world's largest: the world's tungsten resources are mainly concentrated in the Alps Himalayas, the Pacific Rim geological belt and the Mediterranean and Europe's coastal Atlantic region.
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Production reduction and price protection: tough tungsten price meets strong support
Tungsten industry giant's strong production reduction and constant consumption of inventory in price protection industry
On May 17, 2019, China Tungsten Industry Association, together with ten presidium members, spontaneously held an industry Symposium. The output of tungsten concentrate of the participating enterprises reached 86% of the national annual output. It was decided that this year's combined production reduction of tungsten concentrate should not be less than 10%.
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Deep analysis of tungsten industry: from the teeth of industry to the backbone of high-end manufacturing
Tungsten: steel gray or silver white, high hardness, strong ductility, melting point up to 3410 ℃, free from air erosion at room temperature, good conductivity and thermal conductivity, usually used as steel, alloy, lighting or chemical production materials.
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Crystal Chemistry of Tungsten
Scheelite is an intermediate member of the complete homogeneous series of tungsten iron ore (FeWO4)-tungsten manganese ore (MnWO4). Theoretical Composition (ωB/%): tungsten iron FeO 23.65,WO376.35; tungsten manganese MnO 23.42,WO3 76.58.
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Tungsten ores
Tungsten is a widely distributed element, almost all over the rocks, but the content is low. The ore deposit can be formed as commercial ore mining through the enrichment of relevant geological action.
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New discovery of gold, silver and tungsten deposits in Wangjiatai, Suixian County, Hubei Province
The Hubei Geological Survey found a new small tungsten deposit in Wangjiatai area of Suixian. Six gold, silver and tungsten polymetallic ore bodies were preliminarily delineated in the mining area. The total WO334 resources verified by engineering are estimated to be 5752 t, which further broadens the prospecting direction of altered rock type and quartz vein type gold, silver and tungsten polymetallic ore in Suibei area.
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Peanut production key fertilizer, molybdenum fertilizer and boron fertilizer can not be less, when spraying effect is good?
I. Seedling stage, mainly supplemented with molybdenum and boron
Peanut molybdenum and boron need to be sufficient, boron deficiency will appear fruit and no kernel phenomenon, gravure fruit and empty shell fruit increase, grain deformity becomes smaller, less flowering results, empty fruit seedless, boron deficiency is generally difficult to find, once the symptoms have been late.
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Demand and supply are tightening and molybdenum prices are expected to continue rising
The gap in molybdenum supply is expected to be 1.33,2.16 and 30300 tons in 2019-2021, and molybdenum prices are expected to continue to rise. By combing the production capacity and business plans of the world's major molybdenum producers, we expect a small increase in global molybdenum production, with the annual compound growth rate of about 1% in the next three years, while the global molybdenum consumption growth rate is expected to remain around 4% in the……
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Global molybdenum consumption
China's crude steel production climbed to 49% in the decade from 2007 to 2017. With China's crude steel production growth and structural optimization, China's molybdenum consumption growth is expected to continue to be higher than the global consumption growth rate.
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The production of alloy steel is highly correlated with the consumption of molybdenum, which is expected to benefit from the continuous growth of the production of alloy steel
In 2018, the production of alloy steel in the national key Youte steel enterprises was 31.57 million tons, an increase of 11% over the same period last year, and the compound growth rate from 2015 to 2018 was as high as 16.5%. Alloy steel is widely used in construction engineering, machinery manufacturing, automobile, ship, nuclear industry, military weapons and equipment industries.
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Demand side: downstream recovery, demand growth sustained
Global molybdenum consumption growth is expected to remain around 4% in 2019-2021. According to the International Molybdenum Industry Association (IMOA), the global molybdenum consumption in 2018 was 264400 tons, an increase of about 4.4 percent over the same period last year, and the global molybdenum consumption in 2017 was 253100 tons, an increase of 8.9 percent over the same period last year, and the annual compound growth rate of global molybdenum consumption in the past decade was 2.2 percent.
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Study on molybdenum depth in nonferrous metals industry report
Molybdenum - Important Adding Element in Steel Industry molybdenum Mo, atomic number 42, with an average content of 0.00011% in the crust, is a silver-white rare metal. Molybdenum is mainly used in iron and steel industry, which can improve the strength, elastic limit, wear resistance and corrosion resistance of steel, accounting for about 80% of the total consumption of molybdenum.
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Application of molybdenum
Application of molybdenum The application of molybdenum in iron and steel industry occupies the leading position, accounting for about 80% of total consumption of molybdenum, followed by chemical industry, accounting for about 10%.
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Comparison of properties of tungsten disulfide and molybdenum disulfide
Molybdenum and tungsten are homogeneous chemical elements. Tungsten is heavier than molybdenum and has more stable chemical properties. What about their sulfide properties?
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"Green" butterfly change of "molybdenum capital of China"
"China's molybdenum capital ", has proven molybdenum reserves first in Asia, scheelite reserves second in the country, molybdenum tungsten mining industry has long been a pillar industry.
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Troubleshooting of argon arc welding machine
The common causes of failure of TIG arc welding machine and its maintenance methods are as follows:
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Molybdenum in food
Adults generally need 0.15~0.3 mg of molybdenum per day. due to the relatively widespread presence of molybdenum in food, such as chrysanthemum, wheat, beans, milk.
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Use of molybdenum
Pure molybdenum wire is used in high temperature electric furnace; molybdenum sheet is used to make radio equipment and X ray equipment; adding molybdenum to alloy steel can improve elastic limit, corrosion resistance and maintain permanent magnetism. Molybdenum is one of the seven micronutrients needed for plant growth and development, without which plants can not survive. Animals and fish, like plants, also need molybdenum.
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Effects of molybdenum elements
In the late 1950s, something strange happened on a New Zealand ranch. At that time, the scenery was not good, grass withered yellow low, some are dying. But a very lush green pasture belt miraculously grew across the pasture.
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Tungsten
Tungsten is a widely distributed element, which is almost common in all kinds of rocks but low in content.
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Application of tungsten alloy as high temperature material
It is not effective to improve the high temperature strength of tungsten simply by solid solution strengthening. However, on the basis of solid solution strengthening, dispersion (or precipitation) strengthening can greatly improve the high temperature strength, ThO2 and precipitation of HfC dispersion particles have the best strengthening effect. Both the w-hf-c and w-tho2 alloys……
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Current status of tungsten steel
Sintering process The sintering molding of tungsten steel is to press the powder into the blank, then heat it into the sintering furnace to a certain temperature (sintering temperature), and maintain a certain time (holding time), and then cool down, so as to obtain the required properties of tungsten steel material.
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Tungsten steel
Tungsten steel, also known as cemented carbide, refers to sintered composites containing at least one metal carbide composition. Tungsten carbide, cobalt carbide, niobium carbide, titanium carbide and tantalum carbide are common components of tungsten steel.
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Tungsten alloy
Filament industry tungsten was first used to make incandescent filament. Colegi (W.D.Coolidge) of the United States in 1909 using tungsten powder pressing, remelting, rotary forging, wire drawing process to make tungsten wire, since then tungsten wire production has been rapid development.
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